Berkeley Engineering

Fall 2002

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Virtual pipeline makes a southern California debut

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Virtual pipeline's southern California debut
averts economic crisis

The Port of Oakland’s roadways could one day be as congested as those linking the Long-Beach-Los Angeles port complex, relieved by the newly completed Alameda Corridor Project Authority transit line. Partnering with Alex Horne (pictured here) and key to his project’s research was the work of doctoral students James Hauri, Marc Beutel, Jennifer Rubrake, and several undergraduates, as well as his long-time collaborator Berkeley alumnus Larry Russell, and Dr. James Roth, now a private consultant in San Francisco, formerly at the Richmond Field Station. Photo: Peg Skorpinski

By Susan Davis

This is environmental chemistry in action," says Berkeley civil and environmental engineer Alex
Horne, speaking of the newly launched Alameda Corridor Line Project—a 20-mile, $2.4 billion railroad track from Long Beach to Los Angeles completed in April.

"The first freight trains began rolling in the spring, and with them, Governor Gray Davis predicts that California’s gross national product will surpass Great Britain’s to become the fifth largest economy in the world," says Horne, referring to his native England. In this instance, the new line links the huge Long Beach-Los Angeles port complex with the major railheads of downtown Los Angeles. "Amazingly, the $157 billion worth of freight moved every year in the past by trucks is expected to double in the next few years now that it can be moved by rail," says Horne.

For years, a daily procession of thousands of diesel-powered trucks have been hauling shipping containers through crowded city streets. In winter 2000, massive excavations of a new 10-mile (33-foot deep, 50-foot wide) lined, concrete transit trench for a rail line were in full swing. The trench promised to solve the congestion, but there were some real problems. "Apart from the numerous construction and geotechnical challenges," says Horne, "out of the blue there appeared a severe environmental restraint that hopelessly stalled the project."

Groundwater seeping into the track’s trench was too salty to be pumped into the local Los Angeles River, and too laden with heavy metals to be put into the Los Angeles estuaries, home to fragile marine animals. "Marine animals are more sensitive to toxicity from metals like copper than their freshwater counterparts," Horne says.

Underwritten with state bonds, if the project remained stalled, the funding would default, significantly lowering the credit rating of the entire state. What’s more, says Horne, each day of stopped work cost the state $500,000 in interest, while up to 17 million gallons of water a day emptied into the trench. "A two-year delay was forecast, and the bonds were to default in three weeks. My students and I used an ecological engineering approach and solved the problem in a week," says Horne, whose research on aquatic systems is internationally known, not to mention his widespread reputation for what he calls "fig leaves," or simple solutions to difficult problems where crisis is smoldering.

Had there been more time, says Horne, a large pipeline for the groundwater could have been built across the city and into the ocean, where sea water would dilute the heavy metals to safe levels. But that was not to be.

Two years ago, Horne and his doctoral student team were studying natural detoxification of copper sediments in Strawberry Creek on campus. There, they discovered that organic matter in water detoxifies heavy metals through "chelation," a natural process that occurs when an organic molecule grabs the free toxic metal, much like a crab’s pincers grabbing food. Horne realized that chelation could bind the heavy metals in the trench’s groundwater. Once the heavy metals were inactive, the "safe" water could flow through existing channels to the estuary and out to the ocean. "You can chemically chelate the metals, rendering them non-toxic. In effect," he says, "the time-consuming construction of a new pipeline to carry the wastes away could be instantly replaced with a ‘virtual pipeline.’"

Rather than natural chelators, like citrate or dead leaf extract, Horne and his team used ethylene-diamine tetra-acetic acid (EDTA), a common ingredient in skin creams, and the strongest artificial chelator available. EDTA would bind the metals more tightly, Horne explains, as well as resist decomposition by bacteria and sunlight for a longer time.

Anyone passing through this area of southern Los Angeles County near Watts or Compton knows that it’s not exactly pristine wilderness— the estuary, which runs through the Dominguez Channel, passes through areas that have seen a hundred years of oil refining and auto manufacture. The heavy metals deposited in the sediments make it one of the state’s most polluted "hot spots." "You can’t imagine a more disconsolate, seemingly non-living system," Horne says. "But marine animals, including oysters, do exist there and we monitored them extensively. The good news is that EDTA had no harmful effect on these indigenous animals."

Despite the project’s completion, Horne wanted to further assist the polluted estuary. "I proposed that for every pound of chelated groundwater metal passed through, that the agency overseeing the project pay for the removal of 1.5 pounds of the polluted estuary’s sediments. I like to fix things," Horne says, "not just come up with computer models and theories. It’s a chance to do some good old-fashioned engineering with a new twist."



FOREFRONT reports on activities in the College of Engineering at the University of California, Berkeley. It features developments of interest to the engineering and scientific communities and to alumni and friends of the College.

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