Berkeley Engineering Home
Volume 2, Issue 2
Feb/March 2002



Outline List

In This Issue
Organic Transistors and the Death of the Bar Code

A Digital Doctor on Your Wrist

The Art of Engineering, The Engineering of Art

From Russia With Love: Isotopes and the Future of Semiconductors

Berkeley Engineering History: Howard Grant Graduates

Archives

2002
January

2001
Nov/Dec
Sept/Oct
July/Aug

Lab Notes, Research from the College of Engineering


Organic Transistors and the Death of the Bar Code

Prof. Subramanian holds a wafer dipped in "liquid gold" Peg Skorpinski photo

Professor Vivek Subramanian holds a wafer that's been dipped in his "liquid gold" to demonstrate its ink-like properties. When he's away from the lab, Subramanian is most likely in his garden. He's in the midst of a multi-year horticultural experiment to cultivate ultra-hot peppers. (Click for larger image.)

The future of the ubiquitous UPC bar code looks grim. In development at UC Berkeley are circuit-laden smart tags printed directly on product packaging that could revolutionize the supply chain, including your weekly trip to the supermarket.

Imagine filling your shopping cart and walking right out of the store past a sensor that automatically identifies what you're buying and instantly charges your credit card. Of course, the store itself would always be fully stocked because the electronically-enabled shelves would take their own inventory and automatically reorder as necessary. Your refrigerator might even generate its own shopping list, perhaps sensing when your milk is sour or you're down to the last egg in the carton.

"We're focused on disposable electronics," says Vivek Subramanian, Department of Electrical Engineering and Computer Sciences professor. "The question is, can we print a circuit on a package that when you ping it with a radio signal, it'll reply 'Hey, I'm a can of soup'? Just as importantly, can we do it very inexpensively?"

For these printable radio frequency identification (RFID) tags to catch on, they need to be dirt cheap - adding less than one-half a cent to the price of existing product packages, Subramanian says. To meet that price point, Subramanian and his research group have embarked on a multi-disciplinary project spanning chemical, electrical, and mechanical engineering. The result is an extraordinary inkjet printer and a family of electronic inks that enable circuits to be patterned onto paper, plastic, or cloth without damaging the material.

An RFID tag consists of passive components - the inductors, capacitors, and wires that handle the communication, interconnection, and power; and active components - the transistors and diodes that modulate and switch the signal to give the device its brains.

"In the long term, you'd like to have a bit of programmability," Subramanian says. "For example, every can of soup could have the same identification number but each batch could be programmed with a different expiry date." To introduce this capability, the group is also working on adding memory to the tags.

Prof. Subramanian with custom ink printer Peg Skorpinski photo

Subramanian works on the custom ink jet printer used to print the "disposable electronics." (Click for larger image.)

At the April meeting of the Materials Research Society, Subramanian's group will present their progress in developing a printed conductor system that could be used to fabricate the RFID tags' power-scavenging and communication circuitry. The key is "liquid gold." Synthesized in Subramanian's laboratory, liquid gold consists of gold nanocrystals that are only 20 atoms across and melt at 100 degrees Celsius, ten times lower than normal.

The gold nanocrystals are encapsulated in an organic shell of an alkanethiol (an organic molecule containing carbon, hydrogen, and sulphur) and dissolved in ink. Then, an inkjet printer - either the group's cannibalized commercial model or one they have built from scratch ‚ deposits the material on the plastic, paper, or fabric in the desired circuit pattern. The liquid gold is also suitable for screenprinting, commonly employed to print product packaging. As the circuit is printed, the organic encapsulant is burned off, leaving the gold as a high-quality conductor.

"Gold is already used in semiconductors and given the amount you need in our system, the raw material cost is not very high," says Subramanian, who is also developing organic electronics for inexpensive plastic screens that could be rolled up and stuffed in a pocket.

The next stage of the research is to develop high-quality printable transistors, probably a year or two away, Subramanian says. One challenge, he explains, is protecting the printed transistors from corrosive oxygen and moisture. In collaboration with the College of Chemistry, the researchers are exploring the use of the same polysiobutylene rubber-type material used in automobile tires as a screenprintable packaging for the printed transistors. In the meantime, Subramanian and his group are studying their current generation of organic transistors and models of what they expect their transistors to look like in the near future.

"We want to know just how good the transistors need to be for the system to work" and stop there, he says. "After all, this project is truly at the intersection of economics and engineering."



Vivek Subramanian's home page

Organic Electronics at UC Berkeley

College of Chemistry


Lab Notes is published online by the Public Affairs Office of the UC Berkeley College of Engineering. The Lab Notes mission is to illuminate groundbreaking research underway today at the College of Engineering that will dramatically change our lives tomorrow.

Lab Notes is written by David Pescovitz.
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© 2002 UC Regents. Updated 2/14/02.